Search results for "ENERGY-TRANSFER RATES"

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Determination of Temperature by Stimulated Raman Scattering of Molecular Nitrogen, Oxygen, and Carbon-Dioxide

1993

0721-7269; We have determined the temperature from SRS spectra of N2-N2, N2-CO2, O2-O2, and CO2-CO2 recorded in wide pressure and temperature ranges. The fitting procedure takes simultaneously into account the Dicke effect and motional narrowing. We have quantified the accuracy of the MEG and ECS-P models for rotational relaxation. The temperature extracted from each model is compared with thermocouple measurements. The influence of vibrational broadening and shifting is discussed in detail.

SPECTROSCOPYCO2 GASNU-1/2-NU-2 FERMI DYADSPECTRARELAXATIONROTATIONALQ-BRANCHBAND SHAPESN-2ENERGY-TRANSFER RATESLAWS
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